Composition Distribution, Damping and Thermal Properties of the Thickness-Continuous Gradient Epoxy/Polyurethane Interpenetrating Polymer Networks

نویسندگان

  • Xuesong Lv
  • Zhixiong Huang
  • Minxian Shi
  • Yun Fan
  • Guanbin Gao
  • Andrew J. Ruys
چکیده

A thickness gradient interpenetrating polymer network (IPN) was easily created that takes advantage of the relatively poor compatibility and curing rates discrepancy between epoxy (EP) and polyurethane (PU). Ultraviolet absorption spectrum (UV-Vis), thermogravimetric (TG), Differential scanning calorimetry (DSC), Dynamic thermomechanical analysis (DMA), Atomic force microscope (AFM) and water contact angle were adopted to characterize this IPN structure. We found that the absorption in visible light region, glass-transition temperatures (Tg), thermal decomposition temperatures (Td) and Derjaguin–Muller–Toporov (DMT) modulus were increasing along with the gradient direction from bottom side to top side of the IPN. While the absorption in ultraviolet region and adhesion force were decreasing along with the gradient direction from bottom side to top side of the IPN. DMA analysis demonstrates that this continuous gradient IPN has a good balance between the damping temperature range and the loss factor which is suitable for using as a self-supporting damping structure.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Synthesis and Characterization of Biodegradable Semi-Interpenetrating Polymer Networks Based on Star-Shaped Copolymers of ɛ-Caprolactone and Lactide

In this paper, the focus is on a new kind of biodegradable semi-interpenetrating polymer networks, which derived from ɛ-caprolactone, lactide, 1,4-butane diisocyanate and ethylenediamine and also its potential has been investigated in soft tissue engineering applications. The polymers were characterized by nuclear magnetic resonance (NMR) spectrometry, fourier transform infrared spectroscopy (F...

متن کامل

Synthesis and Characterization of Biodegradable Semi-Interpenetrating Polymer Networks Based on Star-Shaped Copolymers of ɛ-Caprolactone and Lactide

In this paper, the focus is on a new kind of biodegradable semi-interpenetrating polymer networks, which derived from ɛ-caprolactone, lactide, 1,4-butane diisocyanate and ethylenediamine and also its potential has been investigated in soft tissue engineering applications. The polymers were characterized by nuclear magnetic resonance (NMR) spectrometry, fourier transform infrared spectroscopy (F...

متن کامل

Preparation and Evaluation of Blood Compatibility of Novel Epoxy-Modified Polyurethanes

      In order to prepare polyurethane elastomers with acceptable physical properties and good biocompatibility, novel polyurethane networks were synthesized via curing reaction of epoxy-terminated polyurethane prepolymers (EUPs) with hexamethylene diamine. EUPs were prepared from reaction of glycidol with NCO-terminated polyurethanes (ITPs). ITPs were also synthesized from reaction of one equi...

متن کامل

Effect of nanozeolite 13X on thermal and mechanical properties of Polyurethane nanocomposite thin films

Polyurethane/zeolite 13X nanocomposite films were fabricated using solution casting method. The synthesized nanocomposite films were structurally characterized using SEM, TGA and tensile analysis. SEM images showed appropriate distribution of nanocrystalline zeolite particles within polyurethane matrix. Better thermal stability of nanocomposite films in comparison to neat polyurethane was shown...

متن کامل

Effect of nanozeolite 13X on thermal and mechanical properties of Polyurethane nanocomposite thin films

Polyurethane/zeolite 13X nanocomposite films were fabricated using solution casting method. The synthesized nanocomposite films were structurally characterized using SEM, TGA and tensile analysis. SEM images showed appropriate distribution of nanocrystalline zeolite particles within polyurethane matrix. Better thermal stability of nanocomposite films in comparison to neat polyurethane was shown...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:

دوره   شماره 

صفحات  -

تاریخ انتشار 2017